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PbI2 Crystal

PbI2 Crystal

Catalog Number: ACMA00024784

CAS Number:

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Description

Description PbI2 crystallizes into a CdI2 structure, in which I-anions are arranged in a hexagonal manner, and each Pb2+ cation is alternately layered with 6 I-anions, forming a typical octahedral structure. Repeated I-Pb-I trilayer stacking, in various ways and limited by van der Waals forces, provides a method to achieve monolayer and few-layer flakes by mechanical and chemical exfoliation due to the relatively low interlayer forces between them. Weakly adjacent layers.

Features And Benefits

Features And Benefits The PbI2 crystal product is perfectly layered with a direct band gap of 2.4 eV. Crystals arrive with perfect 0001 cleavage and are grown by floating zone technology for over 4 months to achieve perfect crystallization. PbI2 crystals are highly luminescent and have a guaranteed optical (photoluminescence) response.

Application

Application Energy storage, catalysis, analytical chemistry, mechanics, adsorption, biology, microelectronics, sensors, etc.

Specifications

Synonyms Lead(II) iodide
Molecular Weight 461.01 g/mol
Boiling Point 410 °C (770 °F; 683 K)
Melting Point 872 °C (1,602 °F; 1,145 K)
Purity 99.9999% guaranteed electronic grade
Density 6.16 g/cm3
Solubility insoluble in ethanol, cold HCl
soluble in alkalis, KI solution, methyl isopropyl ketone
Appearance bright yellow crystals
Bandgap 2.4 eV
Characterization Methods Raman, photoluminescence, TEM, EDS
Crystal Structure And Type CdI2 structure
Dimension ~1 cm in size
Electrical Property band gap semiconductor (bulk)
Magnetic Susceptibility -126.5·10-6 cm3/mol
Production Method Bridgman growth; optional Flux zone or chemical vapor transport
Storage Conditions Room temperature and dry
Type Synthetic
Unit Cell Parameters a=b=0.456 nm and c=6.98 nm

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