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Chromium Triiodide (CrI3) Crystal

Chromium Triiodide (CrI3) Crystal

Catalog Number: ACM13569750-1

CAS Number: 13569-75-0

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Description

Description Chromium triiodide is a rare layered transition metal trichalcogenide (TMTCs) ferromagnetic semiconductor. Unlike chromium trichloride, which exhibits 2D-Heisenberg magnetic behavior, CrI3 exhibits stronger magnetic anisotropy, promoting 3D magnetic properties, with a larger van der Waals gap and thus a smaller splitting energy.

Features And Benefits

Features And Benefits The magnetic properties of CrI3 depend on the layer thickness and stacking order. Bulk CrI3 is a ferromagnetic phase with a Curie temperature of 61 K in a rhombohedral stack, while few-layered CrI3 has a layered antiferromagnetic phase with a lower order temperature of 45 K in a monoclinic stack layer.

Application

Application 2D CrI3 is a promising candidate for van der Waals bonded ferromagnetic devices because its ferromagnetism can be preserved when the bulk crystal is exfoliated to its monolayer.

Specifications

Synonyms Chromium (III) iodide
Molecular Weight 432.71 g/mol
Melting Point >600°C
Purity ≥ 99.999%
Appearance Dark green
Bandgap 0.6-0.67 eV
Characterization Methods XRD, Raman, EDX
Classification Transition metal trichalcogenides (TMTCs), 2D semiconductor materials, Nano-electronics, Nano-photonics, Photovoltaic, Materials science
Crystal Structure And Type Trigonal
Dimension ~5 mm
Electrical Property 2D ferromagnetic semiconductor
Production Method Chemical Vapour Transport (CVT)
Type Synthetic

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